I think it's a good idea to have questions open to paying subscribers. Kurtjmac of Far Lands or Bust! fame (http://farlandsorbust.com/) does so; he answers donators' questions while recording episodes.
As I'm just starting out on my own entrepreneurial journey, what would make this interesting to me is just that: How to run a business, and maybe make and sell apps (my pipe dream) etc. for a living.